A naphthyl-substituted pentamethylcyclopentadienyl ligand and its Sm(II) bent-metallocene complexes with solvent-induced structure change.

نویسندگان

  • Takeshi Yatabe
  • Masaki Karasawa
  • Kiyoshi Isobe
  • Seiji Ogo
  • Hidetaka Nakai
چکیده

A naphthyl-substituted pentamethylcyclopentadienyl ligand (Cp(Naph) = η(5)-C(5)Me(4)CH(2)C(10)H(7)) and its Sm(II) complexes [Sm(Cp(Naph))(2)(THF)(x)] (1: x = 2, 2: x = 0) have been prepared and characterised. The solvent-induced reversible conversion between the di-THF solvated purple complex 1 and the un-solvated dark green complex 2 is presented.

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عنوان ژورنال:
  • Dalton transactions

دوره 41 2  شماره 

صفحات  -

تاریخ انتشار 2012